Phosgene (carbonyl chloride), COCl2, is an extremely toxic gas that is used in manufacturing certain dyes and plastics. Phosgene can be produced by reacting carbon monoxide and chlorine gas at high temperatures: CO(g)+Cl2(g)⇌COCl2(g) Carbon monoxide and chlorine gas are allowed to react in a sealed vessel at 478 ∘C. At equilibrium, the concentrations were measured and the following results obtained:
Gas Partial Pressure
(atm)
CO 0.840
Cl2 1.16
COCl2 0.140
What is the equilibrium constant, Kp, of this reaction?
The following reaction was performed in a sealed vessel at 725?C : H2(g)+I2(g)?2HI(g)
Initially, only H2 and I2 were present at concentrations of [H2]=4.00M and[I2]=2.55M. The equilibrium concentration of I2 is 0.0100M . What is the equilibrium constant, Kc, for the reaction at this temperature?

Respuesta :

Answer:

1) 0.1437 is the equilibrium constant,[tex]K_p[/tex] of this reaction.

2) [tex]9.867\times 10^{-6}[/tex]is the equilibrium constant,[tex]K_c[/tex] of this reaction.

Explanation:

1) [tex]CO(g)+Cl_2(g)\rightleftharpoons COCl_2(g)[/tex]

At equilbrium :

Partial pressure of the CO gas = [tex]p_1=0.840 atm[/tex][

Partial pressure of the [tex]Cl_2[/tex] gas = [tex]p_2=1.16 atm[/tex]

Partial pressure of the [tex]COCl_2[/tex] gas = [tex]p_3=0.140 atm[/tex]

Expression of[tex]K_p[/tex] is given by :

[tex]K_p=\frac{p_3}{p_1\times p_2}[/tex]

[tex]=\frac{0.140 atm}{0.840 atm\times 1.16 atm}=0.1437 [/tex]

0.1437 is the equilibrium constant,[tex]K_p[/tex] of this reaction.

2) [tex]H_2(g)+I_2(g)\rightleftharpoons 2HI(g)[/tex]

Initial:

4.00 M    2.55 M      

At equilibrium ;

(4.00-0.0100) M  (2.55-0.0100) M  (0.0100) M  

(3.9900) M  (2.5400) M  (0.0100) M  

Expression of[tex]K_c[/tex] is given by :

[tex]K_c=\frac{[HI]^2}{[H_2][I_2]}[/tex]

[tex]=\frac{(0.0100 M)^2}{3.9900 M\times 2.5400 M}=9.867\times 10^{-6}[/tex]

[tex]9.867\times 10^{-6}[/tex]is the equilibrium constant,[tex]K_c[/tex] of this reaction.

Phosgene is the organic chemical compound with the formula COCl₂. It is a colorless gas; in low concentrations, its odor resembles that of freshly cut hay or grass.

The formula we will use is as follows:-

[tex]k_p = \frac{p_3}{P_2*P_1}[/tex].

The partial pressure of the[tex]CO,\ CL_2,\ and \ COCL_2[/tex] is given in the question. after putting the value into the formula.

[tex]k_p = \frac{0.140}{0.840*1.16}[/tex] , After solving it the value of Kp is 0.1437.

Hence, 0.1437 is the equilibrium constant.

In the second problem, the equilibrium constant is:-

[tex]k_c=\frac{{HI}^2}{H_2*I_2}[/tex], after putting the value,

[tex]k_c=\frac{{0.01}^2}{3.9900*2.5400}[/tex]

The equilibrium constant is:- [tex]9.867 *10^{-6}[/tex]

For more information, refer to the link:-

https://brainly.com/question/14530482