What is the activation energy for a reaction which proceeds 50 times as fast at 400 K as it does at 300 K? Answer in units of J/mol rxn."

Respuesta :

Answer:

Activation energy for the reaction is 39029J/mol

Explanation:

Arrhenius equation is an useful equation that relates rate of reaction at two different temperatures as follows:

[tex]ln\frac{K_2}{K_1} = \frac{-Ea}{R} (\frac{1}{T_2} -\frac{1}{T_1} )[/tex]

Where K₁ and K₂ are rate of reaction, Ea is activation energy and R is gas constant (8.314J/molK

If the reaction at 400K is 50 times more faster than at 300K:

K₂/K₁ = 50 where T₂ = 400K and T₁ = 300K:

[tex]ln50 = \frac{-Ea}{8.314J/molK} (\frac{1}{400K} -\frac{1}{300K} )[/tex]

[tex]ln 50 = 1x10^{-4}Ea[/tex]

Ea = 39029 J/mol

Activation energy for the reaction is 39029J/mol

Lanuel

The activation energy for this chemical reaction is equal to 39,029.24 J/mol.

Given the following data:

  • Rate of reaction = 50
  • Final temperature = 400 K
  • Initial temperature = 300 K

Ideal gas constant, R = 8.314 J/molK

To determine the activation energy for this chemical reaction, we would use the Arrhenius' equation:

Mathematically, Arrhenius' equation is given by the formula:

[tex]ln\frac{K_2}{K_1} = \frac{-E_a}{R} (\frac{1}{T_2} - \frac{1}{T_1})[/tex]

Where:

  • K is the rate of chemical reaction.
  • [tex]E_a[/tex] is the activation energy.
  • R is the ideal gas constant.
  • T is the temperature.

Substituting the given parameters into the formula, we have;

[tex]ln50 = \frac{-E_a}{8.314} (\frac{1}{400} - \frac{1}{300})\\\\3.9120 = \frac{-E_a}{8.314} (\frac{-1}{1200})\\\\3.9120 = \frac{E_a}{9976.8} \\\\E_a = 9976.8 \times 3.9120\\\\E_a = 39,029.24 \;J/mol[/tex]

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