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When a 16.8 mL sample of a 0.410 M aqueous hydrocyanic acid solution is titrated with a 0.408 M aqueous sodium hydroxide solution, what is the pH after 25.3 mL of sodium hydroxide have been added?
pH =

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From the calculations and results obtained, the pH of the solution is 12.85. This implies that the solution is basic or we can say it is alkaline.

What is pH?

pH is a scale that shows the acidity or alkalinity of a solution.

Number of moles of hydrogen cyanide =  0.410 M *  16.8 /1000 L = 0.0069 moles

Number of moles of NaOH = 0.408 M  * 25.3/1000 L = 0.01 moles

Since the reaction is 1:1, hydrogen cyanide is the limiting reactant.

Number of moles of NaOH left over = 0.01 moles - 0.0069 moles  

= 0.0031 moles

Total volume = 16.8 mL + 25.3 mL = 42.1 mL  or 0.042 L

Molarity of left over hydroxide ions = 0.0031 moles /0.042 L

= 0.07 M

pOH = - log(0.07 M) = 1.15

pH = 14 - 1.15 = 12.85

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