A buffer solution buffer containing 0.32 M HC2H2O2 and 0.14 M KC2H2O2 has a pH of 4.41. What is the pKa of the acid

Respuesta :

The pKa of the acid is 4.05

Calculation of pKa:

pKa tells about the strength of acidic molecule.

[tex]pK_{a}= -log[K_a][/tex]

Where Ka is the dissociation constant of an acid.

According to Henderson-Hasselbalch equation:

[tex]pH= pK_{a} + log\frac{[salt]}{[acid]} \\[/tex]

pH= 4.41

Concentration of acid= 0.32M

Concentration of salt= 0.14M

Putting the values in the equation,

[tex]4.41= pK_{a} + log\frac{0.32}{0.14}\\\\4.41= pK_{a} + 0.36\\\\pK_{a}= 4.41 - 0.36\\pK_{a}= 4.05[/tex]

The pKa of the acid is 4.05.

Learn more about Henderson-Hasselbalch equation:

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